HSN stands for Harmonized System of Nomenclature. It is a system for classifying commodities created by the World Customs organization. U.S. LTL shipping, however, uses NMFC classifications instead.
Freight classification groups products based on similar density, stowability, handling and liability so carriers and shippers have an effective way of communicating the ease of transporting said freight.
Yes. If your shipment can be stacked, it allows the carrier to fit more freight into their truck.