HSN stands for Harmonized System of Nomenclature. It is a system for classifying commodities created by the World Customs organization. U.S. LTL shipping, however, uses NMFC classifications instead.
Adding NMFC code to a shipment is technically optional, but the NMFC codes can help avoid reclassification and ensure you're using the correct freight class number.
Some items, such as car transmissions, have a specific class no matter how heavy or big they are. This is called a fixed class. Items can be assigned a fixed class if the value and transportability very rarely change.